@Article{GonçalvesBaldChiqBere:2018:SyOrSb,
author = "Gon{\c{c}}alves, Rosana Alves and Baldan, Maur{\'{\i}}cio
Ribeiro and Chiquito, Adenilson Jos{\'e} and Berengue, Olivia
Maria",
affiliation = "{Universidade Estadual Paulista (UNESP)} and {Instituto Nacional
de Pesquisas Espaciais (INPE)} and {Universidade Federal de
S{\~a}o Carlos (UFSCar)} and {Universidade Estadual Paulista
(UNESP)}",
title = "Synthesis of orthorhombic Sb2O3 branched rods by a vapor–solid
approach",
journal = "Nano-Structures and Nano-Objects",
year = "2018",
volume = "16",
pages = "127--133",
month = "Oct.",
keywords = "Sb2O3, Vapor–solid growth, Branched microrods, Semiconductor.",
abstract = "In this work, Sb2O3 nanorods, microrods and crystals were
synthesized by a carbothermal reduction driven vaporsolid(VS)
process. Aiming to provide data on the structure of these samples
XRD, FEGSEM and Raman spectroscopy were used. As result, we found
that samples collected at the hottest growth zone (630-760
\◦C) are composed by microrods showing branched morphology
(nanometric branches) and orthorhombic phase of Sb2O3. A cubic
Sb2O3 phase was detected in samples collected at the intermediate
growth zone (440-510 \◦C) and at the coldest growth zone
(180-250 \◦C). The examination of Raman selection rules in
both orthorhombic and cubic samples revealed solid evidences of
the presence of native defects, which we believe to be oxygen
vacancies. Symmetric Schottky barriers were constructed to
orthorhombic Sb2O3samples and the main electrical features of the
devices such as barriers height \ΦB = 0.44 eV and ideality
factor n = 1.03 for Au/Ti contacts were found. The
temperaturedependent resistance measurements have confirmed for
the first time a semiconductor-like behavior in orthorhombic Sb2O3
structures.",
doi = "10.1016/j.nanoso.2018.05.008",
url = "http://dx.doi.org/10.1016/j.nanoso.2018.05.008",
issn = "2352-507X",
language = "en",
targetfile = "goncalves-synthesis.pdf",
urlaccessdate = "27 abr. 2024"
}